Class 12 Chemistry Unit 8 – Aliphatic Hydrocarbons (Alkanes, Alkenes & Alkynes) Complete Notes

Hydrocarbons are organic compounds made up of only carbon (C) and hydrogen (H) atoms. Due to the catenation property of carbon, a large number of hydrocarbons exist.

Aliphatic hydrocarbons are classified based on bond type and saturation:

  1. Alkanes (Paraffins) – Saturated hydrocarbons with only single bonds.
  2. Alkenes – Unsaturated hydrocarbons with a double bond.
  3. Alkynes – Unsaturated hydrocarbons with a triple bond.

So:

  • If all carbon valencies are fully satisfiedSaturated (Alkanes)
  • If carbon valencies are not fully used and contain double/triple bonds → Unsaturated (Alkenes & Alkynes)

💡 Tip for Students:

  • Saturated → Maximum hydrogen atoms attached
  • Unsaturated → Fewer hydrogen atoms

📥 Download Class 12 Chemistry Unit 8 – Aliphatic Hydrocarbons Notes

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FAQ – Aliphatic Hydrocarbons (Class 12 Chemistry Unit 8)

Q1: What are aliphatic hydrocarbons?
A: Aliphatic hydrocarbons are organic compounds made up of carbon and hydrogen only. They can be saturated (alkanes) or unsaturated (alkenes and alkynes) based on their bond types.

Q2: What is the general formula of alkanes, alkenes, and alkynes?

  • Alkanes: CₙH₂ₙ₊₂ (single bonds, saturated)
  • Alkenes: CₙH₂ₙ (double bond, unsaturated)
  • Alkynes: CₙH₂ₙ₋₂ (triple bond, unsaturated)

Q3: How are alkanes different from alkenes and alkynes?

  • Alkanes: Saturated, single bonds only
  • Alkenes: Unsaturated, contain at least one double bond
  • Alkynes: Unsaturated, contain at least one triple bond

Q4: What is the meaning of saturated and unsaturated hydrocarbons?

  • Saturated: All carbon valencies are fully satisfied (maximum hydrogen attached)
  • Unsaturated: Carbon valencies are not fully satisfied (contain double or triple bonds)

Q5: How is the nomenclature of aliphatic hydrocarbons done?
It is based on IUPAC rules, considering:

  1. Length of the carbon chain
  2. Type and position of double or triple bonds
  3. Substituents attached to the chain

Q6: Give an example of each type of aliphatic hydrocarbon.

  • Alkane: Methane (CH₄), Ethane (C₂H₆)
  • Alkene: Ethene (C₂H₄), Propene (C₃H₆)
  • Alkyne: Ethyne (C₂H₂), Propyne (C₃H₄)

Q7: Why are hydrocarbons important?
Hydrocarbons are fuels, raw materials for plastics, solvents, and industrial chemicals. They are essential in daily life and industry.


📝 MCQs – Aliphatic Hydrocarbons 

1. Which of the following is a saturated hydrocarbon?
(a) Ethene
(b) Ethyne
(c) Ethane ✅
(d) Propene

2. The general formula of alkenes is:
(a) CₙH₂ₙ₊₂
(b) CₙH₂ₙ ✅
(c) CₙH₂ₙ₋₂
(d) CₙHₙ

3. Which hydrocarbon contains a triple bond?
(a) Alkane
(b) Alkene
(c) Alkyne ✅
(d) Aromatic hydrocarbon

4. The IUPAC name of CH₃–CH₂–CH₃ is:
(a) Propane ✅
(b) Propene
(c) Propyne
(d) Methane

5. Unsaturated hydrocarbons include:
(a) Alkanes
(b) Alkenes and Alkynes ✅
(c) Only Alkanes
(d) Only Alkynes

6. Which of the following is correct for saturated hydrocarbons?
(a) They contain double bonds
(b) All carbon valencies are fully satisfied ✅
(c) They contain triple bonds
(d) They are reactive like alkenes

7. The molecular formula of ethyne is:
(a) C₂H₄
(b) C₂H₂ ✅
(c) C₂H₆
(d) C₃H₆

8. Which of the following is a property of alkanes?
(a) Highly reactive
(b) Saturated hydrocarbons ✅
(c) Contains double bonds
(d) Contains triple bonds

9. What type of bond is present in alkenes?
(a) Single bond
(b) Double bond ✅
(c) Triple bond
(d) Both single and triple bonds

10. Which of the following is used as a fuel and solvent?
(a) Alkynes
(b) Alkanes ✅
(c) Alkenes
(d) Aromatic hydrocarbons

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